CuWO4 as a cost-effective electrocatalyst for urea oxidation reaction

  • Sreekanth, Thupakula Venkata Madhukar; 
  • Prasad, Kumcham; 
  • Yoo, Jihyung; 
  • Kim, Jonghoon; 
  • Yoo, Kisoo
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초록

The urea oxidation reaction (UOR) plays a critical role in hydrogen (H2) production and in purifying urea-rich wastewater. However, the widespread application of UOR is restricted by the scarcity of low-cost and efficient electrocatalysts. In this study, inexpensive copper tungstate (CuWO4) catalysts were successfully synthesized using a simple hydrothermal synthesis method in the presence of cetrimonium bromide (CTAB) and polyvinylpyrrolidone (PVP) surfactants; the synthesized electrocatalysts were denoted as CW-2 and CW-3, respectively. CW-2 and CW-3 were analyzed via XRD, XPS, FTIR, SEM, and TEM. The CW-3 electrocatalyst shows the lower (430 mV) overpotential, compared with CW-2 electrocatalyst (486 mV) in OER analysis.

키워드

Surfactants; Hydrothermal; Electrocatalyst; UOR; CuWO4; COPPER TUNGSTATE NANOPARTICLES; EFFICIENT; ELECTROOXIDATION; NANOSTRUCTURES; CATALYST; FOAM
제목
CuWO4 as a cost-effective electrocatalyst for urea oxidation reaction
저자
Sreekanth, Thupakula Venkata Madhukar; Prasad, Kumcham; Yoo, Jihyung; Kim, Jonghoon; Yoo, Kisoo
DOI
10.1016/j.inoche.2023.110933
발행일
2023-08
유형
Article
저널명
Inorganic Chemistry Communications
권
154
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1 ~ 7