다층 소결메쉬 확산체를 이용한 알칼라인 수전해 셀

Multi-Layered Sintered Porous Transport Layers in Alkaline Water Electrolysis
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  • 윤영화
  • 최승욱
  • 권지희
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초록

The porous transport layer (PTL) is essential to effectively remove oxygen and hydrogen gas from the electrode surface at high current density operation conditions. In this study, the effect of PTL with different characteristics such as pore size, pore gradient, interfacial coating was investigated by multi-layered sintered mesh. A water electrolysis single cell of active area of the 34.56 cm2 was constructed, and IV performance and impedance analysis were conducted in the range of 0 to 2.0 A/cm2. It was confirmed that the multi-layered sintered mesh PTL, which have an average pore size of 25 to 57 µm and a larger pore gradient, removed bubbles effectively and thus seemed to improve IV performance. Also, it was confirmed that the catalytic metals such as Ni, NiMo coating on the PTL reduced activation overpotential, but increased mass transport overpotential.

키워드

알칼라인 수전해확산체물질 전달과 전압성능 평가전기화학적 임피던스 분광법Alkaline water electrolysisPorous transport layersMass transport overpotentialPorarization curveElectrochemical impedance spectroscopy
제목
다층 소결메쉬 확산체를 이용한 알칼라인 수전해 셀
제목 (타언어)
Multi-Layered Sintered Porous Transport Layers in Alkaline Water Electrolysis
저자
염상호윤영화최승욱권지희이세찬이재훈이창수김민중김상경엄석기김창희조원철조현석
DOI
10.7316/KHNES.2021.32.6.442
발행일
2021-12
저널명
한국수소및신에너지학회논문집
32
6
페이지
442 ~ 454