Thermally stable current-collecting silver grid coated with ceramic-capping layer for low-temperature solid oxide fuel cells

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초록

In an effort to decrease the operating temperature of solid oxide fuel cells (SOFCs), nano-porous thin Pt layers have been used as a cathode material with catalytic activity. Because of porous and thin characteristic of the Pt cathode, however, a large cathode area results in a significant performance deterioration because of the increased sheet resistance of the Pt cathode. In this study, we developed a Ag-patterned grid as a current-collecting layer and a samaria-doped ceria (SDC) oxide-capping layer on the porous Pt cathode to decrease sheet resistance and enhance electrochemical performance. Enhanced electron transportation and thermo-stable behavior of fabricated fuel cells indicated three-fold enhanced peak power density and more than two-fold thermomechanical stability, as per scanning electron microscopy (SEM) and electrochemical analysis results.

키워드

Thermal barrier coating; Samaria-doped ceria (SDC); Oxide-capping layer; Silver current collector; Low-temperature solid oxide fuel cells; YTTRIA-STABILIZED ZIRCONIA; GADOLINIA-DOPED CERIA; HIGH-PERFORMANCE; THIN-FILMS; ELECTROLYTE; DEPOSITION; SOFC; FABRICATION; PLATINUM; CATHODES
제목
Thermally stable current-collecting silver grid coated with ceramic-capping layer for low-temperature solid oxide fuel cells
저자
Hong, Soonwook; Lim, Yonghyun; Prinz, Fritz B.; Kim, Young-Beom
DOI
10.1016/j.ceramint.2018.08.340
발행일
2018-12
유형
Article
저널명
Ceramics International
권
44
호
18
페이지
22212 ~ 22218