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The Hydrodeoxygenation of 2-Methoxyphenol over Ni/Kieselguhr Catalysts as a Model Reaction for Bio-oil Upgrading
- Jeon, J. -K.;
- Huh, B.;
- Lee, C. H.;
- Suh, D. J.;
- Suh, Y. -W.;
- 외 2명
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2초록
Ni/kieselguhr catalysts were applied to hydrodeoxygenate 2-methoxyphenol as a model reaction for bio-oil upgrading in a batch reactor at 100 degrees C and 1.36 MPa. The Ni(40 wt%)-MgO(1.8 wt%)/kieselguhr showed much higher activity in the 2-methoxyphenol hydrodeoxygenation, which could be attributed to the optimal nickel particle size, surface area, and reducibility of the catalyst. Of the Na2CO3 + Urea, NaHCO3, and (NH4)2CO3 precipitants, the Na2CO3 + Urea showed the highest activity because the dispersion and surface area of nickel, rather than the pore size of the catalyst, seems to play an important role in the 2-methoxyphenol hydrodeoxygenation.
키워드
bio-oil; hydrodeoxygenation; 2-methoxyphenol; MgO; Ni; kieselguhr; HYDROGENATION; PYROLYSIS
- 제목
- The Hydrodeoxygenation of 2-Methoxyphenol over Ni/Kieselguhr Catalysts as a Model Reaction for Bio-oil Upgrading
- 저자
- Jeon, J. -K.; Huh, B.; Lee, C. H.; Suh, D. J.; Suh, Y. -W.; Heo, H. S.; Park, Y. -K.
- 발행일
- 2013-02
- 유형
- Article
- 권
- 35
- 호
- 3
- 페이지
- 271 ~ 277