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Thieme Chemistry Journal Awardees - Where Are They Now? Diastereoselective Tandem Iodocarbonate Cyclization of 1,5-Enynes
- Lim, Choongmin;
- Rao, M. Shesha;
- Shin, Seunghoon
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20초록
A diastereoselective, metal-free tandem iodocarbonate-cyclization of 1,5-enyne, emulating the reactivity of gold catalysis is described. The normal selectivity of iodonium reagents for alkene is reversed favoring alkyne activation in the presence of aryl alkynes.
키워드
enynes; iodocyclization; IBr; tandem reactions; diastereoselectivity; CATALYZED CASCADE REACTIONS; TERT-BUTYL CARBONATES; GOLD(I)-CATALYZED FORMATION; ORGANIC-SYNTHESIS; DOMINO REACTIONS; GOLD; CYCLOISOMERIZATION; ENYNES; IONS; N'-(2-ALKYNYLBENZYLIDENE)HYDRAZIDES
- 제목
- Thieme Chemistry Journal Awardees - Where Are They Now? Diastereoselective Tandem Iodocarbonate Cyclization of 1,5-Enynes
- 저자
- Lim, Choongmin; Rao, M. Shesha; Shin, Seunghoon
- 발행일
- 2010-02
- 유형
- Article
- 저널명
- Synlett
- 호
- 3
- 페이지
- 368 ~ 373
- 언어
- ENG
- 출판사
- GEORG THIEME VERLAG KG
- 발행국가
- 독일
- 분량
- 6 페이지
- ISSN
- E 1437-2096
P 0936-5214