Successful Desine of Unique (Single-Crystal-to-Single-Crystal) Diels-Alder Cycloadditions. Change-Trance Forces in the Self Assembly of Heteromolecular Reactive Solids

초록

Electron donor/accepptor (EDA) Interactions are found to be a versatile methodology for the engineering of reactive heteromolecular crystals. In this way, a series of the change-trancefer b-complexes between bis(alkylimino)-1,4-dithin acceptors and anthracene donors are show to form heteromolecular(1:1) crystalline solids that spontaneously undergo stereoselective [2+4] Diels-Alder cycloadditions.