Development of strong, tough and flame-retardant phenolic resins by using Acacia mangium tannin-functionalized graphene nanoplatelets

초록

Constructing an eco-friendly phenolic resin with high toughness, strength, and flame retardancy is of great significance and challengeable in the wood-based panels industry. Acacia mangium tannin (AMT), as a biological macromolecule, was decorated onto graphene through ball milling. The formed AMT-functionalized graphene nanoplatelets (AMT@GnPs) were used to replace 40 % phenol to greenly modify and reinforce phenolic resins. The fabricated phenolic resin (BGTPF) exhibited high wet bonding strength of 1.58 MPa, high tensile strength of 24.4 MPa, and large toughness of 0.35 MJ m−3, which were 38.6 %, 27.7 %, and 75.0 % increments compared with the 1.14 MPa, 19.1 MPa and 0.20 MJ m−3 of the neat AMT-modified phenolic resin (TPF). These improvements were attributable to the good compatibility and strong interfacial interactions between AMT@GnPs and the resin matrix, which promoted the transfer and dissipation of load energy. The prepared BGTPF resin showed good flame retardancy and high thermal stability. The peak HRR decreased from 15.5 for TPF to 6.9 W/g for BGTPF. This work presents a new, low-cost, and sustainable strategy to construct mechanically strong, tough, and flame-retardant tannin-based phenolic resins for many promising applications such as engineered wood-based products.

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