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초록
We synthesized [6,6,6]- and [6,6,7]-tricyclic compounds via intramolecular [4+2] cycloaddition by gold or copper catalysts. Substrates for cyclization were prepared by coupling reactions between eight types of diyne and four types of aromatic moieties. We have successfully synthesized eleven tricyclic compounds.
키워드
catalysis; [4+2] cycloaddition; abietane; Dendrobium; [6,6,m]-cyclic compound; copper; gold; 1-oxomiltirone; abietane derivative; alkyne derivative; aromatic amine; arucadiol; chemical compound; copper; dendrodevonin A; gold; herbaceous agent; unclassified drug; [6,6,6] tricyclic compound; [6,6,7] tricyclic compound; [6,6,m]tricyclic compound; alkylation; Article; benzannulation reaction; bromination; catalysis; chemical reaction; coupling factor; cyclization; cycloaddition; Dendrobium; drug structure; ethynylation; hydrogen bond; methylation; synthesis
- 제목
- Synthesis of [6,6,m]-Tricyclic Compounds via [4+2] Cycloaddition with Au or Cu Catalyst
- 저자
- Kang, Juyeon; Ham, Seunghwan; Seong, Chaehyeon; Oh, Chang Ho
- 발행일
- 2021-06
- 유형
- Article
- 저널명
- Synlett
- 권
- 32
- 호
- 10
- 페이지
- 1039 ~ 1043