A self-assembled Ni(cyclam)-BTC network on ITO for an oxygen evolution catalyst in alkaline solution

Leem, Yun Jin; Cho, Keumnam; Oh, Kyung Hee; Han, Sung-Hwan; Nam, Ki Min; Chang, Jinho

doi:10.1039/c6cc08787f

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A self-assembled Ni(cyclam)-BTC network on ITO for an oxygen evolution catalyst in alkaline solution

Leem, Yun Jin;
Cho, Keumnam;
Oh, Kyung Hee;
Han, Sung-Hwan;
Nam, Ki Min;
... Chang, Jinho

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13

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13

초록

A self-assembled Ni(cyclam)-BTC film was formed on ITO in an acidic solution. Ni(cyclam)-BTC exhibited an enhanced electrocatalytic property for the oxygen evolution reaction (OER), which was strongly relevant to the Ni(III)/Ni(IV) redox reaction activated by the potential dynamic process. A possible formation mechanism of Ni(cyclam)-BTC by self-assembly on ITO was also proposed.

키워드

THIN-FILM ELECTROCATALYSTS; WATER OXIDATION; CYCLIC VOLTAMMETRY; NICKEL-HYDROXIDE; REDUCTION; COBALT; CO2; METAL; IRON; XPS

제목: A self-assembled Ni(cyclam)-BTC network on ITO for an oxygen evolution catalyst in alkaline solution

저자: Leem, Yun Jin; Cho, Keumnam; Oh, Kyung Hee; Han, Sung-Hwan; Nam, Ki Min; Chang, Jinho

DOI: 10.1039/c6cc08787f

발행일: 2017-03

유형: Article

저널명: Chemical Communications

권: 53

호: 24

페이지: 3454 ~ 3457