Synthesis and electrochemical properties of nanorod-shaped LiMn1.5Ni0.5O4 cathode materials for lithium-ion batteries

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초록

Nanorod-shaped LiMn1.5Ni0.5O4 cathode powders were synthesized by a co-precipitation method with oxalic acid. Their structures and electrochemical properties were characterized by SEM, XRD and galvanostatic charge-discharge tests. The resulting nanorod-shaped LiMn1.5Ni0.5O4 cathode active materials delivered a specific discharge capacity of 126 mAhg(-1) at 0.1 C rate. These active materials exhibited better capacity retention and higher rate performance than those of LiMn1.5Ni0.5O4 cathode powders with irregular morphology.

키워드

OxidesNanostructuresChemical synthesisElectrochemical propertiesCOPRECIPITATION METHODLINI0.5MN1.5O4 SPINELELEVATED-TEMPERATURESSTORAGE PERFORMANCEMANGANESE OXIDEDENSITYCARBONATE
제목
Synthesis and electrochemical properties of nanorod-shaped LiMn1.5Ni0.5O4 cathode materials for lithium-ion batteries
저자
Ju, Seo HeeKang, Yun ChanSun, Yang KookKIM, DONG WON
DOI
10.1016/j.matchemphys.2011.11.042
발행일
2012-01
유형
Article
저널명
Materials Chemistry and Physics
132
1
페이지
223 ~ 227