Use of rice straw-based biochar for batch sorption of barium/strontium from saline water: Protection against scale formation in petroleum/desalination industries

초록

The formation of hard mineral scale deposits (e.g., celestite (SrSO4) and barite (BaSO4)) is the most common problem that hinders sustainable operations of water-flooded oilfield and desalination systems (i.e., membrane fouling) when using poor quality water contaminated with barium (Ba(II)) and strontium (Sr(II)) ions. In this work, nanoscale biochar (similar to 53-712 nm) was synthesized from waste rice straw (cost = 380 to 560 +/- 27 US$/Ton; n = 9) and applied as a protective approach against the formation of mineral scale deposits via adsorptive removal of Ba(II)/Sr(II) contaminants from 30,000 ppm saline wastewater. Adsorption of Ba(II)/Sr(II) ions onto biochar was investigated and optimized as a function of biochar amount, water pH, contact time, temperature, and Sr(II)/Ba(II) ratio using response surface methodology. Based on kinetic and isotherm analyses, the biochar exhibited enhanced potential to capture Sr(II)/Ba(II) ions via weak ion-exchange or pore-filling mechanisms (sorption energy (E) approximate to 0.61-0.89 kJ/mol). A comparison of partition coefficient (PC) values verified that sorption of Sr(II) onto biochar is far superior to that of Ba(II) (PCs of 10.1 and 2.5 mu mol g(-1) mu M-1, respectively). Sorption selectivity was mainly dependent on solution pH and the metallic properties of Ba(II)/Sr(II)(e.g., metal size, speciation, and mobility). Quantitative analysis of treated saline water using electrical conductivity and ion chromatography confirmed the ability of biochar sorbent to remove Ba(II) and Sr(II) ions (97.5%) with pre-desalination (e.g., total salts reduction of 25.7% after 48 h). It is thus recommended to utilize the prepared biochar as a promising pre-desalinating adsorptive medium to inhibit mineral scale formation before oilfield water flooding in the petroleum field and membrane desalination systems.

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