Stimuli-responsive nanoparticle self-assembly at complex fluid interfaces: a new insight into dynamic surface chemistry

초록

The self-assembly of core/shell nanoparticles (NPs) at fluid interfaces is a rapidly evolving area with tremendous potential in various fields, including biomedicine, display devices, catalysts, and sensors. This review provides an in-depth exploration of the current state-of-the-art in the programmed design of stimuli-responsive NP assemblies, with a specific focus on inorganic core/organic shell NPs below 100 nm for their responsive adsorption properties at fluid and polymer interfaces. The interface properties, such as ligands, charge, and surface chemistry, play a significant role in dictating the forces and energies governing both NP-NP and NP-hosting matrix interactions. We highlight the fundamental principles governing the reversible surface chemistry of NPs and present detailed experimental examples in the following three key aspects of stimuli-responsive NP assembly: (i) stimuli-driven assembly of NPs at the air/liquid interface, (ii) reversible NP assembly at the liquid/liquid interface, including films and Pickering emulsions, and (iii) hybrid NP assemblies at the polymer/polymer and polymer/water interfaces that exhibit stimuli-responsive behaviors. Finally, we address current challenges in existing approaches and offer a new perspective on the advances in this field. Current advances in designing stimuli-responsive core/shell nanoparticle assemblies focus on reversible nanoparticle surface chemistry and experimental methods for air/liquid, liquid/liquid, and polymer interfaces.

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