The synthesis of asymmetric 1,3-diol via alkenyldialkylborane in the presence of metal alkoxide

초록

the reaction of alkenylalkoxydialkylborate with aldehyde was carried out. We have obtained the useful method of asymmetric 1,3-alkandiol synthesis which is five-membered ring formation with aldehyde via hydroboration from doubl and triple bond in the presence of metal alkoxide.