Sn-based Chalcogenide Composite as a High-Capacity Anode Material for Lithium Rechargeable Batteries

  • Lee, Youngmin
  • Bae, Suk-Rok
  • Park, Bong Je
  • Shin, Dong Wook
  • Chung, Woon Jin
  • 외 1명
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초록

Sn-based chalcogenide composites (TCC) were synthesized as high-capacity anode materials. SnS formed within TCCs is an active center for Li-intercalation. Electrochemical cycling shows that the SnGeS matrix suppresses the volume expansion that can arise from alloying between Sn and Li as well as the grain growth associated with the low melting temperature of Sn. SnGeS complex phases in an amorphous state can contribute to the high capacity of Sn:GeS (6:4 m/m), possibly suppressing the agglomeration and pulverization of Sn.

키워드

ION BATTERIESELECTROCHEMICAL PROPERTIESTINGLASSNANOPARTICLESPERFORMANCENANOWIRESOXIDESIZE
제목
Sn-based Chalcogenide Composite as a High-Capacity Anode Material for Lithium Rechargeable Batteries
저자
Lee, YoungminBae, Suk-RokPark, Bong JeShin, Dong WookChung, Woon JinKang, Yong-Mook
DOI
10.1111/j.1551-2916.2012.05194.x
발행일
2012-07
유형
Article
저널명
Journal of the American Ceramic Society
95
7
페이지
2272 ~ 2276