Co3Se4 nanosheets embedded on N-CNT as an efficient electroactive material for hydrogen evolution and supercapacitor applications

  • Bose, Ranjith
  • Patil, Bebi
  • Jothi, Vasanth Rajendiran
  • Kim, Tae-Hyun
  • Arunkumar, Paulraj
  • ... Ahn, Heejoon
  • 외 1명
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초록

Co3Se4 on nitrogen doped carbon nanotube (N-CNT) with applications for supercapacitor and hydrogen evolution reaction (HER) is synthesized by pyrolysis and solvothermal processes. The catalyst due to improved electrical conductivity and increased rate of removal of H-2 liberated, delivers a high HER activity, by reaching eta(10) at 174 mV arid 240 mV, Tafel slope of 73.2 and 43.8 mV dec(-1) in alkaline and acidic medium respectively. Co3Se4/N-CNT as supercapacitor electrodes, yields a capacitance of 114 F g(-1) at a 2 mV s(-1) scan rate, with an excellent capacitive retention of 96% of the initial capacitance after 5000 cycles. (C) 2018 The Korean Society of Industrial and Engineering Chemistry.

키워드

Co3Se4Carbon nanotubesHydrogen evolutionElectrocatalystSupercapacitorCATALYTIC-ACTIVITYCRYSTAL-STRUCTURES3D ELECTRODECOBALTGRAPHENEELECTROCATALYSTARRAYNANOWIRESSELENIUMCATHODE
제목
Co3Se4 nanosheets embedded on N-CNT as an efficient electroactive material for hydrogen evolution and supercapacitor applications
저자
Bose, RanjithPatil, BebiJothi, Vasanth RajendiranKim, Tae-HyunArunkumar, PaulrajAhn, HeejoonYi, Sung Chul
DOI
10.1016/j.jiec.2018.04.013
발행일
2018-09
유형
Article
저널명
Journal of Industrial and Engineering Chemistry
65
페이지
62 ~ 71