Synthesis and spectral properties of tetraquinoxalinoporphyrazines containing benzocrown-ether group

Song, Cheol Jun; Jang, Chun Keun; Park, Jong Min; Jung, Chang Young; Yao, Wang; Gu, Yeon Ju; Jaung, Jae Yun

doi:10.1142/S1088424613500946

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Synthesis and spectral properties of tetraquinoxalinoporphyrazines containing benzocrown-ether group

Song, Cheol Jun;
Jang, Chun Keun;
Park, Jong Min;
Jung, Chang Young;
Yao, Wang;
... Jaung, Jae Yun;
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초록

The synthesis and spectral properties of the metal-free and the Mg complex derivatives of crown-substituted tetraquinoxalinoporphyrazine are described. Porphyrazine 4 and 5 have satisfactory solubility in chlorinated hydrocarbons, THF and toluene, but are practically insoluble in alcohols. Porphyrazine 5 generally did not show aggregation in CHCl3 but aggregate in DMF.

키워드

tetraquinoxalinoporphyrazine; quinoxaline; Wittig reaction; alpha-diketone; benzo-crown-ether; chelating agent; COPPER PHTHALOCYANINE; AGGREGATION BEHAVIOR; 2,3-DICHLORO-5,6-DICYANOPYRAZINE

제목: Synthesis and spectral properties of tetraquinoxalinoporphyrazines containing benzocrown-ether group

저자: Song, Cheol Jun; Jang, Chun Keun; Park, Jong Min; Jung, Chang Young; Yao, Wang; Gu, Yeon Ju; Jaung, Jae Yun

DOI: 10.1142/S1088424613500946

발행일: 2013-11

유형: Article

저널명: Journal of Porphyrins and Phthalocyanines

권: 17

호: 11

페이지: 1134 ~ 1138

언어: ENG

출판사: WORLD SCI PUBL CO INC

발행국가: 미국

분량: 5 페이지

ISSN: E 1099-1409
P 1088-4246