Synthesis of Cyclohexene Derivatives from 1,5-Enynes via Gold-Catalysis and Iodocyclization: A Comparative Study and Applications in the Synthesis of 7/5-or 8/5-Fused Rings and Biaryls

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초록

A comparative study on the Au(I)-catalyzed and IBr-promoted tandem cyclization of 1,5-enyne was reported. This study provides a meaningful mechanistic insight to the concerted nature of this tandem reaction and also provides interesting applications in the synthesis of 7/5- or 8/5-fused bicycles and biaryls.

키워드

Gold catalysisIodocyclizationTandem reaction1,5-EnyneCarbocyclesASYMMETRIC REACTIONSBRIDGED HALONIUMHALOGEN ADDITIONCYCLIZATIONLIGANDMOPCARBONATESALCOHOLS
제목
Synthesis of Cyclohexene Derivatives from 1,5-Enynes via Gold-Catalysis and Iodocyclization: A Comparative Study and Applications in the Synthesis of 7/5-or 8/5-Fused Rings and Biaryls
저자
Lee, YoungunLim, ChoongminKim, SunghwanShin, Seunghoon
DOI
10.5012/bkcs.2010.31.03.670
발행일
2010-03
유형
Article
저널명
Bulletin of the Korean Chemical Society
31
3
페이지
670 ~ 677

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