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Au(I)-catalyzed intramolecular oxidative cyclopropanation of 1,6-enynes derived from propiolamides with diphenyl sulfoxide
- Yeom, Hyun-Suk;
- Shin, Seunghoon
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38초록
We have developed gold(I)-catalyzed oxidative cyclopropanation of 1,6-enynes derived from propiolamides employing diphenyl sulfoxide as an oxidant. 1,6-Enynes having a terminal alkyne and a propiolamide tether efficiently transformed into cyclopropane carboxaldehyde derivatives.
키워드
IN-SITU GENERATION; INTERMOLECULAR REACTIONS; GOLD; REARRANGEMENT; ALKENES; YLIDES; CYCLOISOMERIZATION; KETONES; ROUTE
- 제목
- Au(I)-catalyzed intramolecular oxidative cyclopropanation of 1,6-enynes derived from propiolamides with diphenyl sulfoxide
- 저자
- Yeom, Hyun-Suk; Shin, Seunghoon
- 발행일
- 2013-02
- 유형
- Article
- 권
- 11
- 호
- 7
- 페이지
- 1089 ~ 1092