Highly Effective Pd-Catalyzed ortho Olefination of Acetanilides: Broad Substrate Scope and High Tolerability

Kim, Byung Seok; Jang, Chungsik; Lee, Dong Jin; Youn, So Won

doi:10.1002/asia.201000613

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Highly Effective Pd-Catalyzed ortho Olefination of Acetanilides: Broad Substrate Scope and High Tolerability

Kim, Byung Seok;
Jang, Chungsik;
Lee, Dong Jin;
Youn, So Won

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61

초록

Bring it on! An effective Pd-catalyzed ortho olefination of various acetanilides has been developed. This transformation has a broad substrate scope and wide functional-group tolerability, regardless of the electronic and steric properties of acetanilide substrates, providing a straightforward access to highly functionalized arenes.

키워드

acetanilides; C-H activation; olefination; palladium; C-H ACTIVATION; CROSS-COUPLING REACTIONS; N BOND FORMATION; DIRECT ARYLATION; SIMPLE ARENES; FUNCTIONALIZATION; REACTIVITY; ANILIDES; CARBON; PALLADIUM(II)

제목: Highly Effective Pd-Catalyzed ortho Olefination of Acetanilides: Broad Substrate Scope and High Tolerability

저자: Kim, Byung Seok; Jang, Chungsik; Lee, Dong Jin; Youn, So Won

DOI: 10.1002/asia.201000613

발행일: 2010-11

유형: Article

저널명: Chemistry - An Asian Journal

권: 5

호: 11

페이지: 2336 ~ 2340