Functionalized metal-organic frameworks for heavy metal ion removal from water

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초록

Water purification is becoming increasingly important due to the scarcity and industrial contamination of water. Although traditional adsorbents such as activated carbon and zeolites can remove heavy metal ions from water, they have slow kinetics and low uptake. To address these problems, metal-organic framework (MOF) adsorbents have been developed, which are characterized by facile synthesis, high porosity, designability, and stability. Water-stable MOFs, such as MIL-101, UiO-66, NU-1000, and MOF-808, have attracted considerable research interest. Thus, in this review, we summarize the developments of these MOFs and highlight their adsorption performance characteristics. Moreover, we discuss functionalization methods that are typically used to improve these MOFs' adsorption performance. This minireview is timely and will help readers understand the design principles and working phenomena of next-generation MOF-based adsorbents.

키워드

RETICULAR SYNTHESIS; POST-SYNTHESIS; GIANT PORES; THIOL; MOFS; DESIGN; STABILITY; ACID; SIZE
제목
Functionalized metal-organic frameworks for heavy metal ion removal from water
저자
Lam, Iris Tsz Yan; Choi, Seon-Jin; Lu, Dong; Kim, Yoonseob
DOI
10.1039/d3nr02250a
발행일
2023-06
유형
Review; Early Access
저널명
Nanoscale
권
15
호
24
페이지
10189 ~ 10205