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MnCo₂O₄ spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditions
- Mishra, Dinesh Kumar;
- Lee, Hye Jin;
- Kim, Jinsung;
- Lee, Hong-Shik;
- Cho, Jin Ku;
- ... Suh, Young-Woong;
- 외 2명
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197초록
A new class of MnCo2O4 spinel supported Ru catalyst, Ru/MnCo2O4, was exploited to afford the highest yield of FDCA (99.1%) from base-free air-oxidation of HMF in water. The catalyst Ru/MnCo2O4 having both Lewis and Bronsted acidic active sites greatly enhanced the FDCA yield. The catalyst was recyclable up to five successive runs without considerable loss of its original activity.
키워드
SELECTIVE AEROBIC OXIDATION; 2,5-FURANDICARBOXYLIC ACID; MESOPOROUS MNCO2O4; BIOMASS; CONVERSION; REDUCTION; WATER; ALCOHOL; CARBON; 5-HMF
- 제목
- MnCo₂O₄ spinel supported ruthenium catalyst for air-oxidation of HMF to FDCA under aqueous phase and base-free conditions
- 저자
- Mishra, Dinesh Kumar; Lee, Hye Jin; Kim, Jinsung; Lee, Hong-Shik; Cho, Jin Ku; Suh, Young-Woong; Yi, Yongjin; Kim, Yong Jin
- 발행일
- 2017-04
- 유형
- Article
- 저널명
- Green Chemistry
- 권
- 19
- 호
- 7
- 페이지
- 1619 ~ 1623