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Aryl Hydrazide beyond as Surrogate of Aryl Hydrazine in the Fischer Indolization: The Synthesis of N-Cbz-indoles, N-Cbz-carbazoles, and N,N '-Bis-Cbz-pyrrolo[2,3-f]indoles
- Park, In-Keol;
- Suh, Sung-Eun;
- Lim, Byeong-Yun;
- Cho, Cheon-Gyu
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74초록
Aryl hydrazides underwent the Fischer indolization reactions, while the N-carbamate group(s) remained intact to directly provide N-Cbz-indoles. This new method allowed the synthesis of various N-Cbz-carbazoles and N,N'-bis-Cbz-pyrrolo[2,3-f]indoles.
키워드
REARRANGEMENT REACTIONS; EFFICIENT SYNTHESIS; CATALYZED REACTIONS; DIRECT OXIDATIONS; AZOBENZENES; SYSTEM; ROUTE; FUNCTIONALIZATION; REGIOSELECTIVITY; HETEROCYCLES
- 제목
- Aryl Hydrazide beyond as Surrogate of Aryl Hydrazine in the Fischer Indolization: The Synthesis of N-Cbz-indoles, N-Cbz-carbazoles, and N,N '-Bis-Cbz-pyrrolo[2,3-f]indoles
- 저자
- Park, In-Keol; Suh, Sung-Eun; Lim, Byeong-Yun; Cho, Cheon-Gyu
- 발행일
- 2009-12
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 11
- 호
- 23
- 페이지
- 5454 ~ 5456