Improvement of the Cycling Performance of LiNi0.6Co0.2Mn0.2O2 Cathode Active Materials by a Dual-Conductive Polymer Coating

Ju, Sea Hee; Kang, Ik-Su; Lee, Yoon-Sung; Shin, Won-Kyung; Kim, Saheum; Shin, Kyomin; Kim, Dong-Won

doi:10.1021/am404965p

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Improvement of the Cycling Performance of LiNi0.6Co0.2Mn0.2O2 Cathode Active Materials by a Dual-Conductive Polymer Coating

Ju, Sea Hee;
Kang, Ik-Su;
Lee, Yoon-Sung;
Shin, Won-Kyung;
Kim, Saheum;
... Kim, Dong-Won;
외 1명

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198

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204

초록

LiNi0.6Co0.2Mn0.2O2 cathode materials were surface-modified by coating with a dual conductive poly(3,4-ethylenedioxythiophene)-co-poly(ethylene glycol) (PEDOT-co-PEG) copolymer, and their resulting electrochemical properties were investigated. The surface-modified LiNi0.6Co0.2Mn0.2O2 cathode material exhibited a high discharge capacity and good high rate performance due to enhanced transport of Li+ ions as well as electrons. The presence of a protective conducting polymer layer formed on the cathode also suppressed the growth of a resistive layer and inhibited the dissolution of transition metals from the active cathode materials, which resulted in more stable cycling characteristics than the pristine LiNi0.6Co0.2Mn0.2O2 cathode material at 55 degrees C.

키워드

conductive polymer; surface modification; LiNi0.6Co0.2Mn0.2O2; protective coating; cycling performance; ELECTROCHEMICAL PERFORMANCE; COMPOSITE CATHODE; LITHIUM BATTERIES; INTERCALATION; STABILITY; LIFEPO4; SPINEL; LINI1/3CO1/3MN1/3O2; ELECTROLYTE; SURFACE

제목: Improvement of the Cycling Performance of LiNi0.6Co0.2Mn0.2O2 Cathode Active Materials by a Dual-Conductive Polymer Coating

저자: Ju, Sea Hee; Kang, Ik-Su; Lee, Yoon-Sung; Shin, Won-Kyung; Kim, Saheum; Shin, Kyomin; Kim, Dong-Won

DOI: 10.1021/am404965p

발행일: 2014-02

유형: Article

저널명: ACS Applied Materials and Interfaces

권: 6

호: 4

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