Low temperature steam reforming of methane using metal oxide promoted Ni-Ce0.8Zr0.2O2 catalysts in a compact reformer

  • Kim, Hak-Min
  • Jang, Won-Jun
  • Yoo, Seong-Yeun
  • Shim, Jae-Oh
  • Jeon, Kyung-Won
  • ... Jeon, Byong Hun
  • 외 4명
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33

초록

Metal oxide (MgO, CaO, and La2O3) promoted Ni-Ce0.8Zr0.2O2 catalysts have been applied for low-temperature steam reforming of methane (SRM), and the promoter effect was investigated. The addition of the metal oxides improved the basicity which enhances the resistance coke formation and catalytic activity. Among the prepared catalysts, the NiLa2O3-Ce0.8Zr0.2O2 catalyst exhibited high activity and stability at a very high gas hourly space velocity of 621,704h(-1). This was mainly due to high dispersion of Ni, strong basicity of La2O3, and strong interaction between Ni and La2O3.

키워드

Metal oxideLa2O3PromoterLow-temperature steam reforming of methaneNI-BASED CATALYSTSCARBON-DIOXIDEHYDROGEN-PRODUCTIONNICKEL-CATALYSTSCO PRODUCTIONETHANOLMGOPERFORMANCEGASNI/CE-ZRO2
제목
Low temperature steam reforming of methane using metal oxide promoted Ni-Ce0.8Zr0.2O2 catalysts in a compact reformer
저자
Kim, Hak-MinJang, Won-JunYoo, Seong-YeunShim, Jae-OhJeon, Kyung-WonNa, Hyun-SukLee, Yeol-LimJeon, Byong HunBae, Jong WookRoh, Hyun-Seog
DOI
10.1016/j.ijhydene.2017.11.058
발행일
2018-01
유형
Article
저널명
International Journal of Hydrogen Energy
43
1
페이지
262 ~ 270