상세 보기
Preferential CO oxidation over supported Pt catalysts
- Jeon, Kyung-Won;
- Jeong, Dae-Woon;
- Jang, Won-Jun;
- Shim, Jae-Oh;
- Na, Hyun-Suk;
- ... Jeon, Byong Hun;
- 외 5명
Citations
WEB OF SCIENCE
9Citations
SCOPUS
9초록
Preferential CO oxidation reaction has been carried out at a gas hourly space velocity of 46,129 h(-1) over supported Pt catalysts prepared by an incipient wetness impregnation method. Al2O3, MgO-Al2O3 (MgO=30 wt% and 70 wt%) and MgO were employed as supports for the target reaction. 1 wt% Pt/Al2O3 catalyst exhibited very high performance (X (CO) > 90% at 175 C-A degrees for 100 h) in the reformate gases containing CO2 under severe conditions. This result is mainly due to the highest Pt dispersion, easier reducibility of PtO (x) , and easier electron transfer of metallic Pt. In addition, 1 wt% Pt/Al2O3 catalyst was also tested in the reformate gases with both CO2 and H2O to evaluate under realistic condition.
키워드
Preferential CO Oxidation; Pt/Al2O3; Dispersion; Reducibility; Electron Transfer; GAS SHIFT REACTION; CARBON-MONOXIDE; SELECTIVE OXIDATION; HYDROGEN-PRODUCTION; METAL CATALYSTS; H-2-RICH GAS; H-2; PROX; PERFORMANCE; PLATINUM
- 제목
- Preferential CO oxidation over supported Pt catalysts
- 저자
- Jeon, Kyung-Won; Jeong, Dae-Woon; Jang, Won-Jun; Shim, Jae-Oh; Na, Hyun-Suk; Kim, Hak-Min; Lee, Yeol-Lim; Jeon, Byong Hun; Kim, Seong-Heon; Bae, Jong Wook; Roh, Hyun-Seog
- 발행일
- 2016-06
- 유형
- Article
- 권
- 33
- 호
- 6
- 페이지
- 1781 ~ 1787