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Intramolecular Fischer Indole Synthesis and its Combination with an Aromatic [3,3]-Sigmatropic Rearrangement for the Preparation of Tricyclic Benzo[cd]indoles
- Park, In-Keol;
- Park, Jun;
- Cho, Cheon-Gyu
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72초록
At the end of the tether: Aryl hydrazides that have carbonyl groups tethered at the para position of the aromatic ring undergo an intramolecular Fischer indolization reaction to give the corresponding indolophanes. Strategic insertion of a double bond in the tether enables a tandem aromatic [3,3] sigmatropic rearrangement reaction to occur to give tricyclic benzo[cd]indoles.
키워드
aryl hydrazides; benzo[cd]indoles; Fischer indole synthesis; polycycles; sigmatropic rearrangement; ARYL HYDRAZIDES; ENANTIOSELECTIVE SYNTHESIS; CONSTRUCTION; AZOBENZENES; STRATEGY; SYSTEM
- 제목
- Intramolecular Fischer Indole Synthesis and its Combination with an Aromatic [3,3]-Sigmatropic Rearrangement for the Preparation of Tricyclic Benzo[cd]indoles
- 저자
- Park, In-Keol; Park, Jun; Cho, Cheon-Gyu
- 발행일
- 2012-03
- 유형
- Article
- 권
- 51
- 호
- 10
- 페이지
- 2496 ~ 2499