Enhanced electrochemical performance of silicon-based anode material by using current collector with modified surface morphology

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초록

Cycle-life of the mixed silicon-graphite composite electrode, with a specific capacity of about 800 mAh/g, for lithium-ion batteries has significantly been improved by using a Cu current collector with a properly modified surface morphology. Especially, it is found that the electrode slurry-coated on a nodule-type foil exhibits a quite good capacity retention. The enhanced cyclability was attributed to the formation of the micro-columnar structure in the composite electrode layer during charge-discharge cycling. It is suggested that if further optimized current collector system is used with a high-performance Si-based active material, better cycle performance is expected.

키워드

lithium-ion batterysiliconSi/graphite compositeanodecycle performanceNANOCOMPOSITE ANODESCYCLE PERFORMANCEION BATTERIESSNCOMPOSITESALLOYTINELECTRODESPOWDERS
제목
Enhanced electrochemical performance of silicon-based anode material by using current collector with modified surface morphology
저자
Kim, Young-LaeSun, Yang-KookLee, Sung-Man
DOI
10.1016/j.electacta.2008.01.050
발행일
2008-05
유형
Article
저널명
Electrochimica Acta
53
13
페이지
4500 ~ 4504