High-Energy Ni-Rich Cathode Materials for Long-Range and Long-Life Electric Vehicles

초록

Li-ion batteries (LIBs) in electric vehicles (EVs) are usually operated intermittently and maintained at high states of charge (SoCs) for long periods. Because the internal particles of Ni-rich cathodes are easily exposed to the electrolyte at high SoCs owing to mechanical instability, the electrolyte exposure time-during which highly reactive Ni4+ ions react with the electrolyte-critically affects the degradation of the cathode. Here, 1 mol% B doping of a core-shell concentration gradient (CSG) Li[Ni0.88Co0.10Al0.02]O-2 cathode (CSG-NCA88) is shown to dramatically alter the microstructure of the cathode and effectively protect the particle interior from parasitic electrolyte attack. The B-doped CSG-NCA88 cathode, CSG-NCAB87, maintains its original microstructure even after holding for 500 h in the fully charged state, whereas irreversible structural damage occurs in the pristine CSG-NCA88 cathode during the prolonged electrolyte exposure. The long-term cycling results confirm that the capacity retention of the cathodes is determined by the electrolyte exposure time at a high SoC and that microstructural modification can effectively suppress the time-dependent degradation from electrolyte attack. The proposed CSG-NCAB87 cathode can be utilized at full capacity without restricting the SoC, thus realizing the development of economical high-energy-density LIBs.

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