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초록
By utilizing the facile formation of an imine from an aldehyde and an amine, we have discovered a new and highly efficient Pd-catalyzed cycloreduction of enediynals leading to the corresponding 2-(2-methylenecycloalkyl)pyrroles in good to excellent yields.
키워드
palladium; endiynal; pyrrole; catalyst; cycloreduction; FURANS; 2-(1-ALKYNYL)-2-ALKEN-1-ONES; CYCLOISOMERIZATIONS
- 제목
- The synthesis of highly functionalized 2-(2-methylenecycloalkyl)pyrroles by palladium-catalyzed cycloreduction
- 저자
- Oh, Chang Ho; Park, Wooram; Kim, Mira
- 발행일
- 2007-06
- 유형
- Article
- 저널명
- Synlett
- 호
- 9
- 페이지
- 1411 ~ 1415