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Acid-Catalyzed [3,3] Sigmatropic Rearrangement of N-Cbz-Diaryl Hydrazide for the Synthesis of Mono-N-Cbz-1,1 '-biaryl-2,2 '-diamine
- Suh, Sung-Eun;
- Park, In-Keol;
- Lim, Byeong-Yun;
- Cho, Cheon-Gyu
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20초록
N-Cbz-Diaryl hydrazides undergo acid-catalyzed [3,3] sigmatropic rearrangement to afford N-Cbz-1,1'-biaryl-2,2'-diamines. The resultant products can be versatile synthetic platforms for a wide variety of C-2- and/or nonsymmetric axially chiral ligands and organocatalysts.
키워드
Sigmatropic rearrangement; Hydrazides; Cross-coupling; Biaryls; Amines; ASYMMETRIC CATALYSIS; COUPLING REACTIONS; AZOBENZENES; BINOL; ROUTE
- 제목
- Acid-Catalyzed [3,3] Sigmatropic Rearrangement of N-Cbz-Diaryl Hydrazide for the Synthesis of Mono-N-Cbz-1,1 '-biaryl-2,2 '-diamine
- 저자
- Suh, Sung-Eun; Park, In-Keol; Lim, Byeong-Yun; Cho, Cheon-Gyu
- 발행일
- 2011-01
- 유형
- Article
- 권
- 2011
- 호
- 3
- 페이지
- 455 ~ 457