Pd-Catalyzed Intramolecular Oxidative C-H Amination: Synthesis of Carbazoles

Youn, So Won; Bihn, Joon Hyung; Kim, Byung Seok

doi:10.1021/ol201416u

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Pd-Catalyzed Intramolecular Oxidative C-H Amination: Synthesis of Carbazoles

Youn, So Won;
Bihn, Joon Hyung;
Kim, Byung Seok

Citations

WEB OF SCIENCE

201

Citations

SCOPUS

210

초록

A Pd-catalyzed oxidative C-H amination of N-Ts-2-arylanilines under ambient temperature using Ozone as an inexpensive, safe, and easy-to-handle oxidant has been developed. This process represents a green and practical method for the facile construction of carbazoles with a broad substrate scope and wide functional group tolerance.

키워드

N BOND FORMATION; TRANSITION-METAL-COMPLEXES; 1ST TOTAL-SYNTHESIS; ORGANIC-SYNTHESIS; REDUCTIVE ELIMINATION; COUPLING REACTIONS; DIRECT ARYLATION; BIARYL SYNTHESIS; PRIMARY AMINES; PALLADIUM

제목: Pd-Catalyzed Intramolecular Oxidative C-H Amination: Synthesis of Carbazoles

저자: Youn, So Won; Bihn, Joon Hyung; Kim, Byung Seok

DOI: 10.1021/ol201416u

발행일: 2011-07

유형: Article

저널명: Organic Letters

권: 13

호: 14

페이지: 3738 ~ 3741

언어: ENG

출판사: AMER CHEMICAL SOC

발행국가: 미국

분량: 4 페이지

ISSN: E 1523-7052
P 1523-7060