Silver(I)-Mediated C-H Amination of 2-Alkenylanilines: Unique Solvent-Dependent Migratory Aptitude

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WEB OF SCIENCE

47
Citations

SCOPUS

50

초록

A highly effective silver(I)-mediated C-H amination of 2-alkenylanilines has been developed to afford a diverse range of substituted indoles. High functional group tolerance, broad substrate scope, simple/fast/high-yielding reaction, and recovery/reuse of the inexpensive silver oxidant are noteworthy. Furthermore, an uncommon migratory process of beta-monosubstituted 2-alkenylanilines with solvent-dependence was demonstrated.

키워드

cyclizationindolesmigrationoxidationsilverPALLADIUM-CATALYZED REACTIONSREGIOCONTROLLED SYNTHESIS4-SUBSTITUTED INDOLESMEDIATED SYNTHESISFUNCTIONALIZATIONCONSTRUCTIONHETEROCYCLESCYCLIZATIONOXIDATIONCONVENIENT
제목
Silver(I)-Mediated C-H Amination of 2-Alkenylanilines: Unique Solvent-Dependent Migratory Aptitude
저자
Youn, So WonKo, Tae YunJang, Min JungJang, Su San
DOI
10.1002/adsc.201400759
발행일
2015-01
유형
Article
저널명
Journal für Praktische Chemie
357
1
페이지
227 ~ 234