Synthesis of Nanoporous Material from Zeolite USY and Catalytic Application to Bio-Oil Conversion

Park, Hyun Ju; Jeon, Jong-Ki; Kim, Ji Man; Lee, Hyung Ik; Yim, Jin-Heong; Park, Junhong; Park, Young-Kwon

doi:10.1166/jnn.2008.1102

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Synthesis of Nanoporous Material from Zeolite USY and Catalytic Application to Bio-Oil Conversion

Park, Hyun Ju;
Jeon, Jong-Ki;
Kim, Ji Man;
Lee, Hyung Ik;
Yim, Jin-Heong;
... Park, Junhong;
외 1명

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31

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33

초록

A highly ordered nanoporous aluminosilicate (MMZ(USY)) was synthesized using commercially available zeolite USY as the framework source and cetyltrimethylammonium bromide as the template. The aluminosilicate was characterized by XRD, N-2 adsorption, ICP-AES and TPD. The catalytic performance of the MMZ(USY) material in the conversion of bio-oil was compared with that of Al-MCM-41, which was synthesized using a direct sol-gel method. The highly accessible nanopores, hydrothermal stability and the intermediate acidic properties of MMZ(USY) correlated with the catalytic performance in the conversion of the bio-oil. The MMZ(USY) used in this study showed excellent activity, selectivity and stability for the production of desirable organic compounds, such as phenolics, with a high degree of deoxygenation.

키워드

MMZ(USY); Catalytic Conversion; Hydrothermal Stability; Phenolics; Deoxygenation; Bio-Oil; STABLE MESOPOROUS ALUMINOSILICATES; BIOMASS PYROLYSIS; BED REACTOR; PALM OIL; FUELS; CHEMICALS; ALKYLATION; CRACKING; HZSM-5

제목: Synthesis of Nanoporous Material from Zeolite USY and Catalytic Application to Bio-Oil Conversion

저자: Park, Hyun Ju; Jeon, Jong-Ki; Kim, Ji Man; Lee, Hyung Ik; Yim, Jin-Heong; Park, Junhong; Park, Young-Kwon

DOI: 10.1166/jnn.2008.1102

발행일: 2008-10

유형: Article; Proceedings Paper

저널명: Journal of Nanoscience and Nanotechnology

권: 8

호: 10

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