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Aerobic oxygenative cleavage of electron deficient C-C triple bonds in the gold-catalyzed cyclization of 1,6-enynes
- Patil, Dilip V.;
- Park, Hyun-Sub;
- Koo, Jaeyoung;
- Han, Jin Wook;
- Shin, Seunghoon
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25초록
Gold-catalyzed aerobic oxygenative cleavage of triple bonds that occurs under the ambient pressure of air and at room temperature is reported; radical inhibition tests suggest that oxygenation occurs via a gold-bound metalloradical intermediate.
키워드
CYCLOADDITION REACTIONS; OXIDATION; CYCLOISOMERIZATIONS; CYCLOBUTENES; (Z)-ENYNOLS; PHOTOREDOX; MECHANISM; CARBENES; COMPLEX; ALKYNE
- 제목
- Aerobic oxygenative cleavage of electron deficient C-C triple bonds in the gold-catalyzed cyclization of 1,6-enynes
- 저자
- Patil, Dilip V.; Park, Hyun-Sub; Koo, Jaeyoung; Han, Jin Wook; Shin, Seunghoon
- 발행일
- 2014-09
- 유형
- Article
- 권
- 50
- 호
- 84
- 페이지
- 12722 ~ 12725
- 언어
- ENG
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 4 페이지
- ISSN
- E 1364-548X
P 1359-7345