Hot-corrosion resistance and phase stability of Yb2O3–Gd2O3–Y2O3 costabilized zirconia-based thermal barrier coatings against Na2SO4 + V2O5 molten salts

  • Song, Dowon; 
  • Song, Taeseup; 
  • Paik, Ungyu; 
  • Lyu, Guanlin; 
  • Kim, Junseong; 
  • 외 2명
Citations

WEB OF SCIENCE

47
Citations

SCOPUS

58

초록

The hot corrosion behavior of plasma-sprayed Yb2O3-Gd2O3-Y2O3 co-doped ZrO2 (YGYZ) coating against Na2SO4 + V2O5 molten salts was investigated and its detailed hot corrosion mechanism was suggested. The chemical reactivity order between the stabilizers was proposed based on the electronic structure and Lewis acid-base mechanism. After hot corrosion, the YGYZ coating exhibited the maintenance of tetragonality ratio and relatively lower extent of destabilization less than 40% of conventional yttria-stabilized ZrO2 coating. These great chemical and phase stabilities imply that YGYZ is promising candidate for high-temperature thermal barrier material.

키워드

Hot corrosion; Rare-earth element; Thermal barrier coatings (TBC); Reaction mechanism; MECHANICAL-PROPERTIES; STRONTIUM ZIRCONATE; DEGREES-C; CONDUCTIVITY; ZRO2; YSZ; CERAMICS; BEHAVIOR; MICROSTRUCTURE; DEGRADATION
제목
Hot-corrosion resistance and phase stability of Yb2O3–Gd2O3–Y2O3 costabilized zirconia-based thermal barrier coatings against Na2SO4 + V2O5 molten salts
저자
Song, Dowon; Song, Taeseup; Paik, Ungyu; Lyu, Guanlin; Kim, Junseong; Yang, SeungCheol; Jung, Yeon-Gil
DOI
10.1016/j.surfcoat.2020.126197
발행일
2020-10
유형
Article
저널명
Surface and Coatings Technology
권
400
페이지
1 ~ 7