Alkoxy transfer reaction of Copper organoborate species to acyl chlorides

초록

Indium-mediated Barbier type allkylation of unsturated cabonyl compound was sturdied. The indium-mediated 1,2-addition reaction of cyclic and acylclic unsturated carbonyl compounds with allyl halide in the presence of indium trichloride were proceeded at room temperature in ether THF of DMF as slovent in high yeilds. The resuts showed that the exclusive 1,2-addition produck were obtainde in this reaction.