Effect of Fumed Silica Nanoparticles on Glass Fiber Filled Thermotropic Liquid Crystalline Polymer Composites

초록

Glass fiber filled thermotropic liquid crystalline polymer (gLCP)/silica composites were prepared by melt compounding. The total torque of the gLCP/silica composites decreased and the melt flow index increased with increasing silica content, which indicates that the fumed silica nanoparticles act as good processing aids and enhance the processing behavior of gLCP/silica composites. The rheological properties of the gLCP/silica composites were significantly dependent on the silica content. The complex viscosity and storage modulus (G') of the gLCP/silica composites decreased with increasing silica content. This was attributed to the ability of the silica nanoparticles to break the glass fiber-glass fiber interactions in the gLCPs. The storage modulus and loss modulus (G '') of the gLCP/silica composites increased with increasing frequency, and the increment was more significant at low frequency. Incorporation of a small quantity of silica nanoparticles improved the thermal stability and mechanical properties of gLCP/silica composites. However, at high silica nanoparticle content the mechanical properties of 9LCP/silica composites decreased because of the aggregation of silica nanoparticles. POLYM. COMPOS., 30:309-317, 2009.

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