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Synthesis and optical properties of tetrapyrazinoporphyrazines containing camphorquinone group
- Jang, Chun Keun;
- Byun, Seung Hwan;
- Kim, Song Hak;
- Lee, Do Kyung;
- Jaung, Jae Yun
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24초록
2,3-dicyanopyrazine and metallophthalocyanines were synthesized with magnesium containing (+/-)camphorquinone substituent. 2,3-dicyanopyrazine was prepared by condensation reaction of diaminomaleonitrile (DAMN) with 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione (1). The tetrapyrazinoporphyrazine was characterized by a combination of UV-visible spectroscopy, fluorescence spectroscopy, infrared radiation, elemental analysis, MALDI-TOF-MS and H-1 NMR spectroscopy.
키워드
camphorquinone; 2,3-dicyanopyrazine; phthalocyanines; spectral properties; fluorescence; aggregation; CIRCULAR-DICHROISM; AGGREGATION; METALLOPHTHALOCYANINES; PHTHALOCYANINES; PORPHYRAZINES
- 제목
- Synthesis and optical properties of tetrapyrazinoporphyrazines containing camphorquinone group
- 저자
- Jang, Chun Keun; Byun, Seung Hwan; Kim, Song Hak; Lee, Do Kyung; Jaung, Jae Yun
- 발행일
- 2009-07
- 유형
- Article
- 권
- 13
- 호
- 7
- 페이지
- 794 ~ 797