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초록
A practical and efficient approach for the total synthesis of arucadiol and 1-oxomiltirone is reported. The key step which involves an intramolecular [4+2] cycloaddition catalyzed by gold(III) bromide or copper(II) triflate leads to the formation of 6-6-6-fused aromatic abietane core.
키워드
arucadiol; 1-oxomiltirone; [4+2]-benzannulation; gold(III) bromide; copper(II) trifluoromethanesulfonate; ABIETANE DITERPENOIDS; BENZANNULATION; EFFICIENT; ACID
- 제목
- Total Synthesis of 1-Oxomiltirone and Arucadiol
- 저자
- Seong, Chaehyeon; Kang, Juyeon; Chai, Uiseong; Mac, Dinh Hung; Oh, Chang Ho
- 발행일
- 2020-12
- 유형
- Article
- 저널명
- Synlett
- 권
- 31
- 호
- 19
- 페이지
- 1953 ~ 1956