A carbon-free ruthenium oxide/mesoporous titanium dioxide electrode for lithium-oxygen batteries

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초록

Mesoporous TiO2 with well-distributed RuO2 catalysts is considered in this paper as a carbon-free cathode material replacement. Benefiting from the highly-porous TiO2 support structure and high catalytic activity of RuO2, the Li-O-2 cells with composite RuO2/mesoporous TiO2 cathodes show low charge potentials with a high cell capacity. The stability of the TiO2 materials was verified by investigating stable cell performance as well as through structural and chemical characterization via X-ray diffraction and Xray photoelectron spectroscopy. This study demonstrates the possibility of achieving high energy at the cell level, free of carbon instability.

키워드

Lithium-oxygen batteries; Titanium dioxide; Catalyst; Ruthenium dioxide; Carbon-free electrode; LI-O-2 BATTERY; CATHODE; OXIDE; CATALYST; ARRAYS; TIO2
제목
A carbon-free ruthenium oxide/mesoporous titanium dioxide electrode for lithium-oxygen batteries
저자
Park, Jin-Burn; Belharouak, Ilias; Lee, Yun Jung; Sun, Yang Kook
DOI
10.1016/j.jpowsour.2015.07.030
발행일
2015-11
유형
Article
저널명
Journal of Power Sources
권
295
페이지
299 ~ 304