A new small molecule acceptor based on indaceno[2,1-b:6,5-b'] dithiophene and thiophene-fused ending group for fullerene-free organic solar cells

  • Xie, Dongjun
  • Liu, Tao
  • Lee, Tack Ho
  • Gao, Wei
  • Zhong, Cheng
  • ... Choi, Hyosung
  • 외 7명
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초록

A new small molecule acceptor of IDTCN with indaceno[2,1-b:6,5-b’]dithiophene as electron-donating core and CPTCN (2-(6-oxo-5,6-dihydro-4H-cyclopenta[c]thiophen-4-lidene)malononitrile) as electron-withdrawing end-capping group was synthesized and investigated in organic solar cells. The IDTCN shows strong and broad absorption with a high extinction coefficient and appropriate energy levels matching with wide bandgap donor polymer. The best device based on PBT1-EH:IDTCN exhibits an open circuit voltage (Voc) of 0.93 V, a short circuit current (Jsc) of 13.31 mA/cm2, a FF of 0.702, achieving a PCE of 8.69%.

키워드

Non-fullerene acceptorsSmall molecule acceptorEnd-capping groupPOWER CONVERSION EFFICIENCYHIGH-PERFORMANCEELECTRON-ACCEPTORSPOLYMERDESIGNINDACENODITHIOPHENEOPTIMIZATIONTEMPERATUREACHIEVE
제목
A new small molecule acceptor based on indaceno[2,1-b:6,5-b'] dithiophene and thiophene-fused ending group for fullerene-free organic solar cells
저자
Xie, DongjunLiu, TaoLee, Tack HoGao, WeiZhong, ChengHuo, LijunLuo, ZhenghuiWu, KailongXiong, WentaoKim, Jin YoungChoi, HyosungSun, YanmingYang, Chuluo
DOI
10.1016/j.dyepig.2017.09.009
발행일
2018-01
유형
Article
저널명
Dyes and Pigments
148
페이지
263 ~ 269