Study on the Cycling Performance of Li4Ti5O12 Electrode in the Ionic Liquid Electrolytes Containing an Additive

  • Kim, Jin Hee
  • Song, Seung-Wan
  • Van Hoang, Hung
  • Doh, Chil-Hoon
  • Kim, Dong-Won
Citations

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초록

The cycling behavior of Li4Ti5O12 electrode in the ionic liquid (IL)-based electrolytes containing 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and a small amount of additive (vinylene carbonate, ethylene carbonate, fluoroethylene carbonate) was investigated. The Li4Ti5O12 electrode in the IL electrolyte with an additive exhibited reversible cycling behavior with good capacity retention. Electrochemical impedance spectroscopy and FTIR studies revealed that an electrochemically stable solid electrolyte interphase was formed on the Li4Ti5O12 electrode in the presence of vinylene carbonate and ethylene carbonate during cycling.

키워드

AnodeIonic liquidLithium ion batteryLi4Ti5O12Solid electrolyte interphaseLITHIUMGRAPHITEANODE
제목
Study on the Cycling Performance of Li4Ti5O12 Electrode in the Ionic Liquid Electrolytes Containing an Additive
저자
Kim, Jin HeeSong, Seung-WanVan Hoang, HungDoh, Chil-HoonKim, Dong-Won
발행일
2011-01
유형
Article
저널명
Bulletin of the Korean Chemical Society
32
1
페이지
105 ~ 108