Synthesis and electrochemical properties of Li[Ni0.45Co0.1Mn0.45-xZrx]O-2 (x=0, 0.02) via co-precipitation method

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초록

Li[Ni0.45Co0.1Mn0.45-xZrx]O-2 (x = 0, 0.02) was synthesized via co-precipitation method. Partial Zr doping on the host structure of Li[Ni0.45Co0.1Mn0.45]O-2 was carried out to improve the electrochemical properties. The Zr-doped Li[Ni0.45Co0.1Mn0.43Zr0.02]O-2 was evaluated in terms of specific discharge capacity, cycling performance and thermal stability. The Zr-doped Li[Ni0.45Co0.1Mn0.45-xZr0.02]O-2 shows the improved cycling performance and stable thermal stability. The major exothermic reaction was delayed from 252.1 degrees C to 289.4 degrees C.

키워드

co-precipitationcathodelithium ion batteryzirconiumBEHAVIORFLUORINE
제목
Synthesis and electrochemical properties of Li[Ni0.45Co0.1Mn0.45-xZrx]O-2 (x=0, 0.02) via co-precipitation method
저자
Bang, Hyun JooPark, Byung-ChonPrakash, JaiSun, Yang Kook
DOI
10.1016/j.jpowsour.2007.06.122
발행일
2007-12
유형
Article; Proceedings Paper
저널명
Journal of Power Sources
174
2
페이지
565 ~ 568