Direct Dehydrative Esterification of Alcohols and Carboxylic Acids with a Macroporous Polymeric Acid Catalyst

Minakawa, Maki; Baek, Heeyoel; Yamada, Yoichi M. A.; Han, Jin Wook; Uozumi, Yasuhiro

doi:10.1021/ol4028495

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Direct Dehydrative Esterification of Alcohols and Carboxylic Acids with a Macroporous Polymeric Acid Catalyst

Minakawa, Maki;
Baek, Heeyoel;
Yamada, Yoichi M. A.;
Han, Jin Wook;
Uozumi, Yasuhiro

Citations

WEB OF SCIENCE

64

Citations

SCOPUS

60

초록

A macroporous polymeric acid catalyst was prepared for the direct esterification of carboxylic acids and alcohols that proceeded at 50-80 degrees C without removal of water to give the corresponding esters with high yield. Flow esterification for the synthesis of biodiesel fuel was also achieved by using a column-packed macroporous acid catalyst under mild conditions without removal of water.

키워드

EFFICIENT ESTERIFICATION; WATER; CONDENSATION; ESTER

제목: Direct Dehydrative Esterification of Alcohols and Carboxylic Acids with a Macroporous Polymeric Acid Catalyst

저자: Minakawa, Maki; Baek, Heeyoel; Yamada, Yoichi M. A.; Han, Jin Wook; Uozumi, Yasuhiro

DOI: 10.1021/ol4028495

발행일: 2013-11

유형: Article

저널명: Organic Letters

권: 15

호: 22

페이지: 5798 ~ 5801