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초록
We have discovered a new method employing Pd-catalyzed cycloreduction of conjugated enynals 1 bearing an alkyne unit leading to the corresponding 2-(2-methylenecycloalkyl)-furans 2a-j and a related compound 7 in good to excellent yields.
키워드
FURANS; CYCLIZATIONS; 2-(1-ALKYNYL)-2-ALKEN-1-ONES; CYCLOISOMERIZATIONS; ACID
- 제목
- Highly functionalized and stereocontrolled syntheses of 2-(2-methylenecycloalkyl)-furan derivatives by Pd-catalyzed cycloreduction
- 저자
- Oh, Chang Ho; Park, Hyun Mi; Park, Dai In
- 발행일
- 2007-03
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 9
- 호
- 7
- 페이지
- 1191 ~ 1193