Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives

초록

Ni-rich layered oxides and Li-rich layered oxides are topics of much research interest as cathodes for Li-ion batteries due to their low cost and higher discharge capacities compared to those of LiCoO2 and LiMn2O4. However, Ni-rich layered oxides have several pitfalls, including difficulty in synthesizing a well-ordered material with all Ni3+ ions, poor cyclability, moisture sensitivity, a thermal runaway reaction, and formation of a harmful surface layer caused by side reactions with the electrolyte. Recent efforts towards Ni-rich layered oxides have centered on optimizing the composition and processing conditions to obtain controlled bulk and surface compositions to overcome the capacity fade. Li-rich layered oxides also have negative aspects, including oxygen loss from the lattice during first charge, a large first cycle irreversible capacity loss, poor rate capability, side reactions with the electrolyte, low tap density, and voltage decay during extended cycling. Recent work on Li-rich layered oxides has focused on understanding the surface and bulk structures and eliminating the undesirable properties. Followed by a brief introduction, an account of recent developments on the understanding and performance gains of Ni-rich and Li-rich layered oxide cathodes is provided, along with future research directions.

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