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Total synthesis of (+/-)-crinine via the regioselective stille coupling and Diels-Alder reaction of 3,5-dibromo-2-pyrone
- Tam, Nguyen Thanh;
- Cho, Cheon-Gyu
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60초록
The regioselective synthesis and Diels-Alder cycloaddition of 3-(3,4-methylenedioxyphenyl)-5-bromo-2-pyrone provided a new synthetic route to crinine. The vinyl bromide group can be used as a handle for further derivatization.
키워드
AMARYLLIDACEAE ALKALOIDS; CYCLOADDITIONS
- 제목
- Total synthesis of (+/-)-crinine via the regioselective stille coupling and Diels-Alder reaction of 3,5-dibromo-2-pyrone
- 저자
- Tam, Nguyen Thanh; Cho, Cheon-Gyu
- 발행일
- 2008-02
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 10
- 호
- 4
- 페이지
- 601 ~ 603