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1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds
- Kim, Ji Hee;
- Ray, Devalina;
- Hong, Chang Seop;
- Han, Jin Wook;
- Oh, Chang Ho
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20초록
Isochromenylium-4-ylplatinum(II) species, generated from 1-(2-alkynylphenyl)hex-5-en-1-ones and Pt(II), reacted with a pendant olefin via [3+2] cycloaddition to form tetracyclic Pt-carbene complexes, which underwent C-H insertion with a benzyloxy group at delta or epsilon positions to give highly complex polycycles, which are otherwise hard to access.
키워드
CONTAINING CARBONYL YLIDES; CATALYZED TANDEM; CYCLIZATION; CONSTRUCTION; GENERATION; ALKENES; ALKYNYL; ETHERS; DERIVATIVES; COMPLEXES
- 제목
- 1,3-Dipolar cycloaddition of 4-platinumisochromenyliums with an olefin and tandem insertion into benzylic C-H bonds
- 저자
- Kim, Ji Hee; Ray, Devalina; Hong, Chang Seop; Han, Jin Wook; Oh, Chang Ho
- 발행일
- 2013-06
- 유형
- Article
- 권
- 49
- 호
- 50
- 페이지
- 5690 ~ 5692