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"On-water" Photochemical Thiol-Ene Reaction of N-Enoxybenzotriazoles
- Jung, Jong In;
- Lee, Jun Sup;
- Shin, Seunghoon
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3초록
We report herein a photochemical thiol-ene coupling using N-enoxybenzotriazoles, significantly accelerated under "on-water" conditions. This approach achieves efficient coupling within just five minutes via a remarkably rapid radical chain reaction, attributed to enhanced EDA formation and accelerated radical addition through a hydrophobic effect. The robustness of this method under various perturbation conditions underscores its potential for broad applications.
키워드
On water; Photocatalysis; Thiol-ene reaction; Radical chain; Catalyst-free; CLICK CHEMISTRY; CATALYSIS; RADICALS; ROUTE
- 제목
- "On-water" Photochemical Thiol-Ene Reaction of N-Enoxybenzotriazoles
- 저자
- Jung, Jong In; Lee, Jun Sup; Shin, Seunghoon
- 발행일
- 2025-10
- 유형
- Article; Early Access
- 저널명
- Synthesis
- 권
- 57
- 호
- 20
- 페이지
- 2963 ~ 2968