Understanding the Synthesis of Ethylene Glycol Pulsed Plasma Discharges

  • Wells, Gabriel Padron
  • Estrada-Raygoza, Isabel Cristina
  • Thamban, P. L. Stephan
  • Nelson, Caleb T.
  • Chung, Chin-Wook
  • 외 2명
Citations

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초록

In the present work, an investigation of the gas and surface phase behavior of ethylene glycol (EG) pulsed discharges is presented. Infrared and optical emission spectroscopy along with time-resolved electron temperature (Te) and electron density (ne) measurements were employed in these pulsed EG plasmas to study the dynamics of monomer fragmentation and effective chemical feedback from boundary walls. Maximized retention of monomer functionality, (CH2CH2O)n, were seen in polymer deposits when processed at low values of average power (<20W). This preservation of monomer functionality is attributed to the increase in effective collision time between electrons and EG molecules. Presented results correlated well with proposed ethylene glycol dissociation pathways in the pulsed discharge.

키워드

biopolymerscold plasmaethylene glycolplasma polymerizationpulsed plasmasREFERENCE CELLSURFACEGASFILMSDEPOSITIONFIBRINOGENCHEMISTRYRESISTANTCOATINGSETHER
제목
Understanding the Synthesis of Ethylene Glycol Pulsed Plasma Discharges
저자
Wells, Gabriel PadronEstrada-Raygoza, Isabel CristinaThamban, P. L. StephanNelson, Caleb T.Chung, Chin-WookOverzet, Lawrence J.Goeckner, Matthew J.
DOI
10.1002/ppap.201200066
발행일
2013-02
유형
Article
저널명
Plasma Processes and Polymers
10
2
페이지
119 ~ 135